Manganese(II) iodide is the chemical compound composed of manganese and iodide with the formula MnI2(H2O)n. The tetrahydrate is a pink solid while the anhydrous derivative is beige. Both forms feature octahedral Mn centers. Unlike MnCl2(H2O)4 and MnBr2(H2O)4 which are cis, MnI2(H2O)4 is trans.
Preparation
Anhydrous MnI2 is prepared from the elements:
- Mn I2 → MnI2
The tetrahydrate can be prepared by treating manganese(II) carbonate with hydriodic acid. The anhydrous form can be produced from it by dehydration in a vacuum.
Properties
Samples turn brown in air under the influence of light as a result of the oxidation of the iodide ion to iodine. It has a trigonal crystal structure of the cadmium iodide type (polytype 2H) with the space group P3m1 (space group no. 164). It dissolves in water and decomposes. The tetrahydrate has a monoclinic crystal structure with the space group P21/c (No. 14).
Applications
It is often used in the lighting industry.
References
